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Strange planes in quartz
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Josele




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PostPosted: Mar 14, 2015 16:58    Post subject: Strange planes in quartz  

Some quartz specimens from Tormik (Pakistan) are quite weird, with troubled growth, multiple terminations and unusual habit. This one has two peculiarities that baffle me:

1 - A semiperimetral inclined plane (I dare not call it face) that can see at top right. Seems be parallel to an "a" axis and cuts "c" axis with an angle clearly more obtuse than a rhombohedral face.

2 - Two parallel grooves seen at low center crossing four of the six prism faces. Planes containing grooves forms an angle with "c" axis similar to plane mentioned in point 1. Those planes seems to be almost parallel to another "a" axis but they not exactly match striation of prism face for about 2-3º.

Thanks for lend a hand.



P1150240.JPG
 Mineral: Quartz
 Locality:
Tormiq Valley, Baltistan District, Gilgit-Baltistan (Northern Areas), Pakistan
 Dimensions: 12 x 6 x 5 cm
 Description:
1 - Can see the plane going down from right to left. When crossing the prism face at left, marks a white line matching striation, although not evident in the picture.

2 - Grooves are up to 6 mm deep at front face.
 Viewed:  32928 Time(s)

P1150240.JPG



P1150241.JPG
 Mineral: Quartz
 Locality:
Tormiq Valley, Baltistan District, Gilgit-Baltistan (Northern Areas), Pakistan
 Dimensions: 12 x 6 x 5 cm
 Description:
Are hard to photograph these transparent, colorless and shiny specimens!
 Viewed:  32937 Time(s)

P1150241.JPG



P1150242.JPG
 Mineral: Quartz
 Locality:
Tormiq Valley, Baltistan District, Gilgit-Baltistan (Northern Areas), Pakistan
 Dimensions: 12 x 6 x 5 cm
 Description:
1 - Here point of view is in the inclined plane located above. Can see that angle of plane and "c" axis is about 60/120º
Little below another cleavage plane-like parallel to first one is glimpsed.

2 - Grooves cross four of the six prism faces.
 Viewed:  32913 Time(s)

P1150242.JPG



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Martin Rich




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PostPosted: Mar 14, 2015 18:17    Post subject: Re: Strange planes in quartz  

May be marks of preexisting calcite crystals?

Martin

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Dale Hallmark




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PostPosted: Mar 14, 2015 18:19    Post subject: Re: Strange planes in quartz  

Maybe someone used a lapidary saw on it for some reason.

Dale
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Jordi Fabre
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PostPosted: Mar 14, 2015 18:36    Post subject: Re: Strange planes in quartz  

Martin Rich wrote:
Maybe marks of preexistent calcite crystals?...

I agree. A similar phenomena happens in Dalnegorsk and it is related with former Calcite crystals. Please check this post of the thread "John S. White collection"
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PostPosted: Mar 14, 2015 19:38    Post subject: Re: Strange planes in quartz  

In some hydrothermal vein environments, and at least some other environments with temperatures much warmer that current conditions, early-formed calcite has a very flat, paper-thin morphology, called Papierspat (paper spar) in German. Other minerals, including quartz and fluorite, then form and grow around the edges of the calcite crystals, which later dissolve, leaving randomly oriented grooves and dents in the later-formed crystals.

I was recently looking at some fluorite from pre-Cambrian lava flows in Minnesota. The fluorite consisted of sub-parallel laths in vugs. The only sensible way to understand them was as what could grow between these calcite plates, and was left behind by their solution.

Some strange irregularly-polyhedral geodes ("polyhedroids") of quartz are similarly interpreted as partial quartz infillings of voids formed between such calcite crystals spanning veins in igneous/metamorphic rocks.

Sorry, no pictures.

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silvio steinhaus




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PostPosted: Mar 15, 2015 01:18    Post subject: Re: Strange planes in quartz  

I have some similar quartz purchased from a prospector in Brazil, from the border of Minas Gerais to Bahia, unknown city.
The cuts in one of the samples looked me possible altered epidotes inclusions, which when cleaned with acid turned out to be totally removed.



IMG_2135.JPG
 Mineral: Quartz
 Locality:
Minas Gerais, Brazil
 Dimensions: 4,5 X 9,0 X 3,5 cm
 Description:
Unknown city.
The photo quality is not good, only made now to be able to comment, subsequently I will provide best photos of this and other pieces acquired from the same prospector.
 Viewed:  32785 Time(s)

IMG_2135.JPG



IMG_2136.JPG
 Mineral: Quartz
 Locality:
Minas Gerais, Brazil
 Dimensions: 4,5 X 9,0 X 3,5 cm
 Description:
The photo quality is not good, only made now to be able to comment, subsequently I will provide best photos of this and other pieces acquired from the same prospector.
 Viewed:  32797 Time(s)

IMG_2136.JPG


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Josele




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PostPosted: Mar 15, 2015 08:17    Post subject: Re: Strange planes in quartz  

Thanks for your very enlightening comments. Myself I have a piece from Bor Pit with these growth interferences but haven't found a relation before you pointed it.
What strikes me now is the fact that these calcite interferences in this thread and many more from this location seem to be in a similar orientation with respect to "c" axis of quartz, forming an angle of about 60º (regardless Silvio's one, which is a epidote interference). I wonder if this is a coincidence or may exist some sort of epitaxial-like reason for this.



P1150305.JPG
 Mineral: Quartz
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Dimensions: 8 x 2 x 1.8 cm
 Description:
This specimen has calcite interferences in two directions. One is parallel to a prism face. The other conforms an angle of about 60º with c axis.
 Viewed:  32716 Time(s)

P1150305.JPG



P1150301.JPG
 Mineral: Quartz
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Dimensions: FoV: about 4 cm
 Description:
 Viewed:  32796 Time(s)

P1150301.JPG



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marco campos-venuti




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PostPosted: Mar 15, 2015 08:59    Post subject: Re: Strange planes in quartz  

This crystal is from China. Interferences can be from Calcite, or maybe from Hematite?
They are also parallel as in the sample of Josele. Maybe better from Calcite.



2426 (Medium).JPG
 Mineral: Quartz crystal on Hematite
 Locality:
Jinlong Hill, Longchuan, Heyuan Prefecture, Guangdong Province, China
 Description:
 Viewed:  32696 Time(s)

2426 (Medium).JPG


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PostPosted: Mar 15, 2015 09:42    Post subject: Re: Strange planes in quartz  

Fascinating!
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Clifford Trebilcock




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PostPosted: Mar 15, 2015 20:01    Post subject: Re: Strange planes in quartz  

Interesting discussion ! A few years ago I came across a small Quartz crystal seam in some metamorphosed schist not far from my home here in Phippsburg, Maine. The crystals look similar to some of the Dalnegorsk Quartz crystals, but on a smaller scale. Some look like stacked coins or caps on stems. Attaching a couple of photos of one specimen.


DSC00002.JPG
 Mineral: Quartz
 Locality:
Phippsburg, Sagadahoc County, Maine, USA
 Dimensions: 3.6 cm x 1.5 cm
 Description:
Interfered growth Quartz crystals
 Viewed:  32544 Time(s)

DSC00002.JPG



DSC00007.JPG
 Mineral: Quartz
 Locality:
Phippsburg, Sagadahoc County, Maine, USA
 Dimensions: 3.6 cm x 1.5 cm
 Description:
View from different angle.
 Viewed:  32584 Time(s)

DSC00007.JPG


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PostPosted: Mar 16, 2015 04:57    Post subject: Re: Strange planes in quartz  

I have long been fascinated by these quartzes which do indeed appear to owe their strange forms to having grown among and around calcite crystals, with the calcite subsequently etched away. However, I was fortunate in having acquired one specimen from the Bor mine in Russia which still contained much of the calcite, see photo. My favorite specimen from the Bor mine is the small one which appears to have grown through a hollow "tunnel" in calcite. At one time these were quite common but are now difficult to find. Finally I am including an example from China, similar to the one shown above, and in my opinion there can be little doubt that calcite influenced the development of these crystals. I do not believe that the angle of the "cuts" in the quartz is constant. I believe it is completely random.

I apologize for the very poor photos. They were taken in great haste.



P1030133.JPG
 Mineral: Quartz with Calcite
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Dimensions: 13 cm
 Description:
Those are calcite crystals at the base of the quartz.
 Viewed:  32523 Time(s)

P1030133.JPG



P1030134.JPG
 Mineral: Quartz
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Dimensions: 5.5 cm
 Description:
 Viewed:  32531 Time(s)

P1030134.JPG



P1030131.JPG
 Mineral: Quartz with Hematite
 Locality:
Jinlong Hill, Longchuan, Heyuan Prefecture, Guangdong Province, China
 Dimensions: FOV 7 cm
 Description:
 Viewed:  32517 Time(s)

P1030131.JPG



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PostPosted: Mar 16, 2015 09:34    Post subject: Re: Strange planes in quartz  

One thing that is interesting about Cliff's specimen and John's last specimen is that one can envisage a single calcite plate inflluencing several well-separated quartz crystals!
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PostPosted: May 15, 2015 15:45    Post subject: Re: Strange planes in quartz  

Here's a specimen I just obtained - almost more groove than quartz!

One interesting thing about this specimen is that the planes preserve a texture of lines or striations that is consistent with the c-axis of calcite - three sets of lines forming equilateral triangles.

Another is that there are two additional sets of grooves oriented in different directions from the main one. Two sets are obvious in the last image. The third one is nearly in the plane of the image, and its location is indicated by the black line drawn just inside of the trace of the groove itself. None of these three directions is parallel to the faces of the quartz.

This crystal is so torn up by the grooves that I cannot figure out what its orientation is!



IMG_5281.JPG
 Mineral: Quartz grooved by calcite
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Dimensions: 3.5 cm in maximum dimension
 Description:
 Viewed:  31598 Time(s)

IMG_5281.JPG



Q1b.jpg
 Mineral: Quartz
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Description:
 Viewed:  31539 Time(s)

Q1b.jpg



grooves.jpg
 Mineral: Quartz
 Locality:
Bor Pit, Dalnegorsk B deposit, Dalnegorsk, Dalnegorsk Urban District, Primorsky Krai, Russia
 Description:
 Viewed:  31621 Time(s)

grooves.jpg



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PostPosted: May 16, 2015 06:30    Post subject: Re: Strange planes in quartz  

A pretty piece! For sure you will find the orientation of the quartz crystal if you spent some time mulling over it. Please, let us know when you find out.

Pete Richards wrote:
... the planes preserve a texture of lines or striations that is consistent with the c-axis of calcite - three sets of lines forming equilateral triangles. ...

Pete, I suppose you mean "... consistent with the a-axis of calcite ...", isn't it?

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PostPosted: May 16, 2015 09:48    Post subject: Re: Strange planes in quartz  

Very pretty in my opinion.
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PostPosted: May 16, 2015 09:53    Post subject: Re: Strange planes in quartz  

Hi,
When I see such quartz, I think recognize the cleavage plane induced by shock or high mechanical pressures. This plane is {10-11}.
Of course afterwards these microfaults can be partially filled with calcite.
Roger.
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PostPosted: May 16, 2015 18:14    Post subject: Re: Strange planes in quartz  

Josele wrote:
Pete, I suppose you mean "... consistent with the a-axis of calcite ...", isn't it?


Thank you, Josele. I did not express myself very clearly. I should have said that the striations are in orientations consistent with the three-fold symmetry of calcite. The striations were on pinacoid faces (0001) of the now-gone calcite, which are perpendicular to the c-axis and thus lie in a plane that is parallel to that defined by the a-axes. Whether the striations are traces of cleavage intersecting that plane or traces of mechanical twinning, they would in fact be parallel to the a-axes.

In the left drawings are calcite with the cleavage rhomb and the pinacoid, both standard clinographic and top views. On the right drawnings are calcite with the negative rhomb {01.2}, which is the mechanical twinning direction, and the pinacoid. In either case, the striations are parallel to the edges between the rhomb and the pinacoid; these are shown in black. The axes are shown in green and the crystal edges in red.



Papierspa.jpg
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Papierspa.jpg



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PostPosted: May 16, 2015 18:30    Post subject: Re: Strange planes in quartz  

Roger Warin wrote:
Hi,
When I see such quartz, I think recognize the cleavage plane induced by shock or high mechanical pressures. This plane is {10-11}.
Of course afterwards these microfaults can be partially filled with calcite.
Roger.


Hi Roger,

I appreciate your comment and am familiar with the cleavage of quartz and with your interest in it. The cleavage plane set {10.1} is parallel to one of the two rhombohedra that typically form the terminations on quartz. In this specimen, one can locate multiple sets of incomplete terminations along specific edges of the quartz plates. None of the sets of grooves are aligned in one of theses directions. The main set is approximately parallel to a prism face, but deviates from parallelism by perhaps 5-10°. Neither of the other two sets is parallel to a rhombohedral face.

In addition, the cleaved quartz I am familiar with does not have multiple parallel cleavages - usually just one cleavage is present, and the cleaved fragment is broken free from the rest of the crystal. Sometimes a shard is bounded by two parallel apparent cleavage surfaces.

It is hard to see how this specimen could be cleaved multiple times, the fragments spread so there is space in between them, but left intact together for the calcite to later invade. Further complicating this theory is that the cracks never go all the way through the crystal - a core region remains intact. I think the detailed evidence rules out cleavage in this case.

Thanks for your interest.

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PostPosted: May 16, 2015 19:28    Post subject: Re: Strange planes in quartz  

Great drawings! thanks for taking the job, without them it would have been difficult to understand. Then striations can have two very different origins, normal {101} and flat {012} rhombohedron can be involved. If it were possible measure the tilting angle of a stria wall...
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PostPosted: May 17, 2015 05:00    Post subject: Re: Strange planes in quartz  

Since this thread has taken on new life I felt I should try to produce a better photo of one of my Bor mine, Dalnegorsk, Russia, specimens. In some ways this specimen is very different from all of the others that I have seen. It still contains much of the calcite that is responsible for the "slices" in the quartz, concentrated at the base of the specimen. It is also responsible, I believe, for the odd termination. The quartz crystal is 11.5 cm long. This photo is an improvement, but it is far from the quality that I would like it to be.


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