View previous topic :: View next topic |
Author |
Message |
Brent Lockhart
Joined: 25 Jan 2012
Posts: 34
Location: Larkspur, Colorado


|
Posted: Feb 27, 2020 23:55 Post subject: Isotopic composition of German Silvers |
|
|
I had a brief conversation with Terry Wallace a few months ago regarding some isotopic constitution work done with German native Silvers, i.e. Himmelsfurst as an example. There probably is some discussion of the question of these specimens being natural versus man made on this forum, but I've not been able to find it. Can anyone point me to any such discussion or any recent publications on this matter? I believe there may be some recent published isotopic work available which would be most helpful.
Cheers
Brent Lockhart _________________ Member of the Colorado Chapter, Friends of Mineralogy |
|
Back to top |
|
 |
Jordi Fabre
Overall coordinator of the Forum

Joined: 07 Aug 2006
Posts: 5029
Location: Barcelona



|
Posted: Feb 28, 2020 14:33 Post subject: Re: Isotopic composition of German Silvers |
|
|
Brent Lockhart wrote: | ...I've not been able to find it. Can anyone point me to any such discussion or any recent publications on this matter?... |
Not directly related about the German silvers but yes about some of the Imiter silvers and indirectly also related with the German ones:
Wire "silvers" from Imiter (Morocco) |
|
Back to top |
|
 |
Brent Lockhart
Joined: 25 Jan 2012
Posts: 34
Location: Larkspur, Colorado


|
Posted: Feb 28, 2020 15:13 Post subject: Re: Isotopic composition of German Silvers |
|
|
Hi Jordi
Thank you for directing me to this discussion, it helps a lot. I am collecting miniatures now, and am trying to think through what species I would include. I used to own a very good Freiburg Silver wire which was about 17 cm, tall, coming out of an important European collection. There was no doubt that this one came out in the 19th century or earlier, and as such was unquestionably natural on its matrix. But now, as in the Moroccan case, there are questions about smaller specimens' authenticity. In this case it is thought that some pieces may be smelter by-products or lab grown. I had not realized that this uncertainty extended to other localities. So I am looking for any good diagnostic tools to verify or debunk these doubts. Thanks again for helping me out.
Cheers
Brent _________________ Member of the Colorado Chapter, Friends of Mineralogy |
|
Back to top |
|
 |
Philip Simmons
Joined: 24 Feb 2011
Posts: 79
Location: Albuquerque, New Mexico



|
Posted: Mar 02, 2020 23:02 Post subject: Re: Isotopic composition of German Silvers |
|
|
Brent Lockhart wrote: | Hi Jordi
Thank you for directing me to this discussion, it helps a lot. I am collecting miniatures now, and am trying to think through what species I would include. I used to own a very good Freiburg Silver wire which was about 17 cm, tall, coming out of an important European collection. There was no doubt that this one came out in the 19th century or earlier, and as such was unquestionably natural on its matrix. But now, as in the Moroccan case, there are questions about smaller specimens' authenticity. In this case it is thought that some pieces may be smelter by-products or lab grown. I had not realized that this uncertainty extended to other localities. So I am looking for any good diagnostic tools to verify or debunk these doubts. Thanks again for helping me out.
Cheers
Brent |
Hi Brent,
John Rakovan has put some serious time into this particular topic. Along with several other authors, he has publish an excellent paper in the July 2019 issue of Geology. It's a bit of a read if you're not familiar with isotope geochemistry, but it explains much. I don't think there are any fool-proof ways to determine if a specimen is lab grown or natural except through silver isotope fractionation. Synthetic (or manufactured) silvers show an enrichment in heavier silver isotopes (109Ag).
Based on my understanding of the article, just because the German silvers are old does not mean they are unquestionably natural. Due to the ionic conductive properties of acanthite, silvers wires can be easily grown where both minerals occur together. You can even grow silver wires on acanthite without removing or changing the acanthite. It's a very interesting topic, and I hope more information will be forthcoming.
I hope this helps clear things up a bit!
Phil |
|
Back to top |
|
 |
Brent Lockhart
Joined: 25 Jan 2012
Posts: 34
Location: Larkspur, Colorado


|
Posted: Mar 02, 2020 23:37 Post subject: Re: Isotopic composition of German Silvers |
|
|
Hi Phil
Thanks for the reference, much appreciated. I really was interested in what isotopic evidence had come out of the recent studies and will find a copy of this article. It will certainly bring into question the nature of most of these wire specimens. The piece I was referring to was out of the Bally Prior Museum, coming to them around WWI. The single wire specimen measured 17 cms long and was some 2 cms. wide near the base. While we can never say never, the odds of some lost technology capable of producing such wires in that time frame seems unlikely. At least I haven't seen a flood of very large wire silvers entering the market yet.
Thanks for the tip, I'll try to muddle my way through the article and appreciate your time replying to my question.
Cheers
Brent _________________ Member of the Colorado Chapter, Friends of Mineralogy |
|
Back to top |
|
 |
Philip Simmons
Joined: 24 Feb 2011
Posts: 79
Location: Albuquerque, New Mexico



|
Posted: Mar 03, 2020 15:32 Post subject: Re: Isotopic composition of German Silvers |
|
|
You're welcome!
It is interesting to see new information regarding this long debated topic. I'm not saying the old German silvers are undoubtedly faked, but it might have been possible that there was a similar situation when compared to the zincites from Poland (at least the ones found from the smelter).
Unfortunately, even scientific research has met with strong (and sometimes powerful) discouragement when topics like this are breached. We shall see if more information comes to light regarding silver wire growth. I love these studies for the scientific information we gain, but when dealing with egos and large sums of money things can get swept under the rug, so to speak. |
|
Back to top |
|
 |
Brent Lockhart
Joined: 25 Jan 2012
Posts: 34
Location: Larkspur, Colorado


|
Posted: Mar 03, 2020 23:08 Post subject: Re: Isotopic composition of German Silvers |
|
|
Yep, the folks who've paid big bucks for Silvers and the dealers who sold them are not gonna like this. As you point out, isotopic quantity measurement is not something every lab can do. A mass spec (or similar) versus an XRD setup cost is not something I have much of a sense for though. There may be some metallurgical labs around able to do it, but I bet it would be expensive. Think I'll be giving wire Silvers a pass. _________________ Member of the Colorado Chapter, Friends of Mineralogy |
|
Back to top |
|
 |
|