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Pete Richards
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Joined: 29 Dec 2008
Posts: 845
Location: Northeast Ohio



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Posted: Dec 31, 2008 10:59 Post subject: Re: Why is this wulfenite silver? |
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Sliding off topic but... Speaking of interesting experiments, put a piece of bornite in dilute HCl in contact with a piece of iron or steel. You'll find that the iron gets coated with metallic copper.
_________________ Collecting and studying crystals with interesting habits, twinning, and epitaxy |
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Les Presmyk
Joined: 06 Dec 2007
Posts: 372
Location: Gilbert, AZ


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Posted: Dec 31, 2008 11:01 Post subject: Re: Why is this wulfenite silver? |
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I have to ask who out there has the time to experiment with acids and rubbing iron nails across crystals to see if they change color besides Alfredo?
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Pete Richards
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Joined: 29 Dec 2008
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Location: Northeast Ohio



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Posted: Dec 31, 2008 11:06 Post subject: Re: Why is this wulfenite silver? |
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It's not like I go around randomly rubbing nails and HCl on things.... >:^)
I discovered the bornite thing by accident when I was trying to remove malachite from some bornite and did the soaking in an old steel pan.
_________________ Collecting and studying crystals with interesting habits, twinning, and epitaxy |
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alfredo
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Joined: 30 Jan 2008
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Posted: Dec 31, 2008 11:10 Post subject: Re: Why is this wulfenite silver? |
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Les, It comes from my previous impoverished low-tech lifestyle in 3rd World villages in the 1970s and 80s; no access to XRD or microprobes. But it's amazing how many low-tech identification techniques one can invent in the kitchen after reading a few chemistry textbooks.
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Les Presmyk
Joined: 06 Dec 2007
Posts: 372
Location: Gilbert, AZ


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Posted: Dec 31, 2008 11:20 Post subject: Re: Why is this wulfenite silver? |
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We should probably go back to some of those tests and techniques. I am never surprised by the resourcefulnes of the human spirit or put another way, necessity is the mother of invention.
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Tracy

Joined: 15 Sep 2006
Posts: 551
Location: Toronto



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Posted: Dec 31, 2008 11:37 Post subject: Re: Why is this wulfenite silver? |
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I can do a peroxide test, bur for lack of proper equipment/chemicals to do the other diagnostics (when next I see you Alfredo I'll bring it with me), I'm going with the temporary premise that the silver is a coating (which in parts has a rippled appearance under a loupe, like paint) and that beneath the silver is a rough-textured, second red coating - suggesting that the crystal, whatever color it is, is coated with hematite or iron oxides. I don't see any smooth areas (besides the silver ones) to tell me with certainty what the color might be beneath all the coating(s). All the same, as an empirical question, is it theoretically possible to have a wulfenite crystal that is included with hematite? Maybe I'll carefully try to scratch one of the red edges (close to where it contacts the matrix), that might help.
I did test it with a magnet and if the stuff is magnetic, it's only very weakly so.
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Peter Megaw
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Joined: 13 Jan 2007
Posts: 973
Location: Tucson, Arizona



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Posted: Dec 31, 2008 13:24 Post subject: Re: Why is this wulfenite silver? |
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Les, given your experiences in Arizona copper mines you should know the old handspecimen trick of putting a couple drops of HCl from your field bottle onto suspected copper-bearing "limonites" and skootching it around with straightpin (knifeblade) to see if copper plates out. fast dirty and very accurate
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Linda St-Cyr

Joined: 29 Oct 2008
Posts: 34
Location: Sparks, Nevada & on the road!



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Posted: Dec 31, 2008 18:11 Post subject: Re: Why is this wulfenite silver? |
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Alfredo & Pete - thank you for some cool ideas for my science museum! Now I have an excuse to save all those little bits of minerals lying around. (Actually I was already saving them to try the ID by flame method.)
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Tracy

Joined: 15 Sep 2006
Posts: 551
Location: Toronto



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Posted: Jan 03, 2009 18:59 Post subject: Re: Why is this wulfenite silver? |
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Peroxide test was negative, and I don't really want to start scraping at it unless I have to...guess I'll have to wait till I can show it to someone...
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David Catalano
Joined: 11 Nov 2009
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Posted: Nov 12, 2009 10:13 Post subject: Re: Why is this wulfenite silver? |
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Hello,
There are a few colors of wulfenite found at Tsumeb, however in early mining operations a blue tinged var. of wulfenite was found. It was known to have a metallic luster. Your specimen looks like bicolor wulfenite. It seems to have sections of color. Awesome piece that you have there. Tsumeb is known for amazing, world class mineral semblances.
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Tracy

Joined: 15 Sep 2006
Posts: 551
Location: Toronto



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Posted: Nov 12, 2009 10:22 Post subject: Re: Why is this wulfenite silver? |
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Thanks for the info David!
- Tracy
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Matt_Zukowski
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Joined: 10 Apr 2009
Posts: 737
Location: Alaska



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Posted: Nov 13, 2009 00:14 Post subject: Re: Why is this wulfenite silver? |
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What a great thread! Interesting chemistry - thanks.
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Val

Joined: 06 May 2009
Posts: 15
Location: Upstate NewYork



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Posted: Nov 13, 2009 16:48 Post subject: Re: Why is this wulfenite silver? |
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I thought you might want to see some photos of my blue Wulfenite from Tsumeb. As you can see it looks metallic with a bluish sheen.
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