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Naica Mine - (11)
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Jordi Fabre
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PostPosted: Jan 21, 2010 03:23    Post subject: Re: Naica Mine - (11)  

OK Master 2.

Anyway, I have a doubt. In https://www.mineral-forum.com/message-board/viewtopic.php?p=9227#9227 you said:
Peter Megaw wrote:
Gibraltar was operated by Eagle Picher Mining until it was purchased by the Fresnillo Mining Company (now Penoles...which spun off the new Fresnillo pls in 2008) in 1955. The Gibraltar name survives as the name of one of the two hoisting shafts, the upper part of which used to service what was the Gibraltar Mine. However, it is inaccurate to call it the Gibraltar Mine. Penoles, has used the Naica name since they acquired and consolidated the district in 1955 and began sulfide production. ALL specimens from the sulfide zone should be labeled Naica Mine.

and this Gypsum is quite old, so it could been mined in the former Gibraltar mine? and if yes, what is adequate, the name that the mine had when the specimen was mined or the current's mine name? ;-)

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PostPosted: Jan 21, 2010 10:01    Post subject: Re: Naica Mine - (11)  

It is possible since the entire mountain seems to be riddled with gypsum pockets...but the Cave of the Swords and sister cavern where most of the historic gypsum specimens came in quantity from were in the Maravilla and Lepanto workings. I used to buy crystals by the carload from the mine manager...they harvested them from the Cave of the Swords, sold them and used th proceeds to pay for the refreshmensts served in the miner's club.

Unless you have some reason to think whoever made the label that goes with this piece really knew which mine it came from, you would probably be safest to put "upper oxide levels" "Naica Mine" on the label, perhaps noting a pre-1955 harvest date.

The mine is almost equally well endowed with anhydrite crystals, they are everywhere... except they don't choke up the pumping system and sumps or line enormous caverns. There has been a fair amount of work done on the origin/source of the gypsum and anhydrite...Google "Naica" and "Geology" and you will be led to the April 2007 article in the scientific journal "Geology" on the subject. Although it does have some significant flaws regarding crystal growth, it shows the that both the gypsum and anhydrite are derived from evaporite beds that occur in the host rock section below the principal limestone units. Both the limestone and anhydrite/avaporite beds at that depth are thoroughly thermally metamorphosed to coarse-grained marble...if that term can be applied to the evaporites. The ore fuids passing through dissolved the "primary" anhydrite and it reprecipitated as anhydrite with sulfides in the orebodies or gypsum on sulfides depending on the temperature. Interestingly the "secondary" anhydrite crystals we see from the mine are sky-blue to grayish blue in color whereas the bedded anhydrite at depth is lilac in color.



naica2.jpg
 Description:
Anhydrite crystal 12 cm long. Naica Mine
 Viewed:  91474 Time(s)

naica2.jpg



bigcrystals4.jpg
 Description:
Giant gypsum crystal from Naica Mine
 Viewed:  91540 Time(s)

bigcrystals4.jpg



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PostPosted: Jan 21, 2010 10:13    Post subject: Re: Naica Mine - (11)  

Peter Megaw wrote:
...would probably be safest to put "upper oxide levels" "Naica Mine" on the label

I agree Master 2 ;-)

Already corrected in: https://www.mineral-forum.com/message-board/viewtopic.php?p=9309#9309
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PostPosted: Apr 18, 2010 16:32    Post subject: Re: Naica Mine - (11)  

A while ago, Peter Megaw wrote:
Jesse...check those fluorite crystals carefully... some have inclusions of curling and curving fibres of an elongate sulfosalt.
(...)
Fluorite, cubic with trisoctahedral modifications with earlier octahedral stage phantom defined by galena crystals.


Here's a Naica fluorite miniature (I had once shown it to Jordi in person) exhibiting all of these traits, as well as some nice calcite / chalcopyrite / sphalerite decorations on the matrix. Acquired by yours truly in October 2009, collection id 09MXFSCc3.
The overall specimen dimensions are 47x42x31mm.

The cube {100} and dodecahedron {110} faces are perfectly smooth, the other faces are frosted.

Stereo photos are in crossed-eyes mode.



09MXFSCc3a.jpg
 Description:
The shape and orientation of the bright {110} face provide the easiest way to deduce that the surrounding faces are {113}. {112} would give the same diamond shape with angles of 70.5° and 109.5° but oriented the other way, acute corners towards the cube face. {114} and higher forms would cut narrower rhombs out of the {110} face.
 Viewed:  90213 Time(s)

09MXFSCc3a.jpg



09MXFSCc3iA.jpg
 Description:
Side view (taken through the microscope), faces labelled with their Miller indices. Field of view 15x11.5mm.
 Viewed:  90212 Time(s)

09MXFSCc3iA.jpg



09MXFSCc3hS.jpg
 Description:
Same in stereo. The octahedral {111} faces are very small. FOV 9x16.7mm.
 Viewed:  90210 Time(s)

09MXFSCc3hS.jpg



09MXFSCc3eS.jpg
 Description:
Stereo view onto the top of the specimen. The interior is very pale green and perfectly transparent. (Note that the cube(001) face is "standing on end" as it were, its edges at 45° to the axes.)
 Viewed:  90236 Time(s)

09MXFSCc3eS.jpg



09MXFSCc3kS.jpg
 Description:
Close-up looking at the inclusions - as far as I can tell, there's both galena (the lustrous octahedra) and sphalerite (the rougher shapeless grains) among them. At this magnification (FOV 10.9x18.1mm), it becomes obvious that they sit on an otherwise almost invisible interior phantom which is mostly octahedral, except the corner pointing towards us is truncated by a small cube face, oriented the same way as the one through which we're looking.
 Viewed:  90172 Time(s)

09MXFSCc3kS.jpg



09MXFSCc3mS.jpg
 Description:
Magnifying even more (FOV 4.3x5.7mm) and looking at one edge of the phantom, whose apex is near the top right corner of the frame, we see that the galena/sphalerite grains rest just on the outside of the phantom shape, while small fibers of metallic luster sit just below the phantom surface.
The outer top face of the Fluorite through which we're looking is almost invisible now! If you look around a bit, you may discover one or two small blemishes on it showing up as bright dots, e.g. one near the lower right-hand edge of this frame.
 Viewed:  90225 Time(s)

09MXFSCc3mS.jpg



09MXFSCc3oS.jpg
 Description:
And one more at high mag (FOV 4.65x5.9mm), looking at the truncated apex of the interior phantom octahedron (a little below and to the right of the center of the frame).
 Viewed:  90300 Time(s)

09MXFSCc3oS.jpg


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PostPosted: Apr 19, 2010 15:53    Post subject: Re: Naica Mine - (11)  

Very often modifying faces on fluorite are misidentified. The usual confusion, when modifying faces of a cube occur in groups of three, is whether the faces belong to a trisoctahedron or a trapezohedron. Since the faces meet at a corner of the cube, where an octahedron would be if it were present, folks often think these faces belong to a trisoctahedron - the thinking being "trisoctahedron" - "three-octahedron" - "three [faces instead of an ] octahedron [face]". In my experience, these modifying faces usually belong to a trapezohedron, {311} being the most common. The Naica Mine fluorites are more complex, and I think Herr Niklasch is right in his analysis. But as a general rule, if the modifying faces appear primarily to cut off the edges of the cube, they belong to a trisoctahedron. If they appear primarily to cut off the faces, they belong to a trapezohedron. In either case, they modify the corner, with three faces replacing one hypothetical faces of an octahedron!

Trapezohedra have the general Miller indices {hkk}, where h is greater than k, e.g. {211}. Trisoctahedra have the general indices {hhk}, where h is greater than k, e.g. {221}. Since all three axes are equivalent in the isometric system, {211} can equally validly be written as {121} or {112}, where the curly brackets mean that the Miller indices represent all faces of the form, not just one face. {211} and {112} are common choices in different regions of the world; I think {121} is rarely if ever used when all three choices are equivalent.

Attached are a couple of drawings.



fluorite.jpg
 Description:
 Viewed:  90164 Time(s)

fluorite.jpg



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PostPosted: Apr 19, 2010 16:20    Post subject: Re: Naica Mine - (11)  

Many thanks for the illuminating diagrams!

Yeah, I had been struggling with the identification for quite a while, and had to throw away several wrongly annotated pictures before coming up with the above.
(Never trust a mathematician who embarks on actual calculation!)

Perhaps it's just me - I'm finding finding myself even more readily confused when these forms modify an octahedron rather than a cube...

Cheers, Gerhard
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PostPosted: Apr 19, 2010 16:47    Post subject: Re: Naica Mine - (11)  

Pete...taking this one step further. Apologizing in advance for the picture...here's a close up of a trapezohedron on a Naica fluorite...modified by a face that cuts off its triple junction. There would be 6 of these in the form, negative octahedron or negative cube...or something else altogether?


Naica trap mod.jpg
 Description:
 Viewed:  42667 Time(s)

Naica trap mod.jpg



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PostPosted: Apr 19, 2010 16:51    Post subject: Re: Naica Mine - (11)  

A few more nica Naica fluorites!


Naica fluorite shelf.jpg
 Description:
Shelf of Naica fluorites
 Viewed:  42705 Time(s)

Naica fluorite shelf.jpg



Naica galena phantom in fluorite.jpg
 Description:
Pocket mate of Gerhard's specimen...6 cm across
 Viewed:  42707 Time(s)

Naica galena phantom in fluorite.jpg



Naica spinel twin fluorite.jpg
 Description:
Naica spinel twinned fluorite...with large enhydro. 8 cm across
 Viewed:  42773 Time(s)

Naica spinel twin fluorite.jpg



Naica oct fluorite 2.jpg
 Description:
Naica octahedron 10 cm on an axis
 Viewed:  42743 Time(s)

Naica oct fluorite 2.jpg



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PostPosted: Apr 19, 2010 16:54    Post subject: Re: Naica Mine - (11)  

A break from fluorite...a couple "seldom-seens"


Naica pyrite worm.jpg
 Description:
Pyrite "worms" on quartz 5 cm across
 Viewed:  42808 Time(s)

Naica pyrite worm.jpg



Naica epidote.jpg
 Description:
Calcite on epidote from Naica
 Viewed:  42746 Time(s)

Naica epidote.jpg



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PostPosted: Apr 19, 2010 17:05    Post subject: Re: Naica Mine - (11)  

Peter Megaw wrote:
here's a close up of a trapezohedron on a Naica fluorite...modified by a face that cuts off its triple junction. There would be 6 of these in the form, negative octahedron or negative cube...or something else altogether?


I think you'll find there are actually eight of these in the form. They belong indeed to an octahedron {111}. I'm not sure whether "negative octahedron" is the correct term (there's only one octahedron under the full symmetry group); but the little triangles are oriented opposite to the full {111} triangles - the trapezohedron cuts off the corners of the latter.

-- And that's a nice Naica gallery you have there!

Cheers, Gerhard
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PostPosted: Apr 20, 2010 04:37    Post subject: Re: Naica Mine - (11)  

An old rule that I remember to help distinguish between the two forms described by Pete is to note the orientation of the Y formed by the faces of the form in the corner of the cube. If the Y is upright, the form is the trapezohedron. If the Y is inverted, we are seeing the trisoctahedron.
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PostPosted: Apr 20, 2010 10:07    Post subject: Re: Naica Mine - (11)  

So...to coin a mnenomic..."Y"es its a Trapezohedron
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PostPosted: Mar 08, 2011 15:47    Post subject: Re: Naica Mine - (11)  

Hi, hope you like this photograph, is a real beauty of Mineral Naica Chihuahua Mexico.


DSC09635.JPG
 Description:
Naica Chihuahua Mexico.
anidrithe, calcite.
 Viewed:  41849 Time(s)

DSC09635.JPG


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PostPosted: May 22, 2013 12:10    Post subject: Re: Naica Mine - (11)  

One new wonderful thread to the Featured Columns of FMF! This time the topic is the Naica Mine (see above)

Please continue developing it, a great mine needs a great thread! ;-)
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PostPosted: May 22, 2013 15:01    Post subject: Re: Naica Mine - (11)  

Beautiful
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