FMF - Friends of Minerals Forum, discussion and message board

[Pierre Joubert]

[Pierre Joubert]

A nice article on the Waller method:

https://pegworkshop.com/extras/waller/waller1.html
(link normalized by FMF)

[ilzho]

Thanks for the information.

I have a few quartz crystals that I am trying to clean as well.

David

[Bob Harman]

I might soak the specimen in soapy water for a day or two, then use a hi pressure spot cleaning gun. Start gently then gradually increase the hi pressure stream to see if it cleans off the surface stuff. I would do this on your specimen as much for experience and practice as anything else as I do not believe in spending a lot of time with examples such as those. The cleaning just doesn't improve quartz specimens like that very much. BOB

[Peter Lemkin]

Stains on quartz from iron-containing minerals are easily removed with oxalic acid, especially warm oxalic acid. Don't use it indoors; don't breath the fumes; do use gloves and use due care. Wash off all of the acid from minerals, gloves, etc. Sometimes, one has to use a few times with new/clean solution if it gets too yellow. However, be careful, as using oxalic can also deposit iron minerals in small cracks within some quartz, so try it out first, but not on your best pieces.

[GneissWare]

Virtually nobody who professionally cleans rocks uses oxalic acid for iron stain removal. In the USA we have a powder called Super Iron Out (SIO), which essentially created a Waller's solution that is very effective at removing iron coatings. It is less toxic and has a pH of about 6.5 so it effective on many things. You can google either SIO or Waller's solution for the chemistry.

[Jordi Fabre]

[Pierre Joubert]

Hi Gneissware. In places like SA, we do not have Super Iron Out, and ordering it from the USA is expensive and problematic. I recently asked a local chemical company for something similar to SIO. I used the product but with very little effect. I bought chemicals to make my own Waller method solution, but this also had no effect. Ronnie Mc Kenzie told me that he has used Aluminium cleaner effectively on some quartzes and I tried it with great effect on quartz specimens with clay from areas that are rich in manganese. It also dissolves manganese coatings on crystals. I tried it and it works well on specimens from mentioned areas.

To David I want to say that your specimen, no matter how insignificant to others, is special to you and clean it as best as you can. If you can get hold of SIO, take Gneissware's advice. If you cannot get hold of it, oxalic acid should do just fine. If your oxalic acid solution is too strong, you will have a yellow staining, which is easily removed with pool acid (careful please with the latter).

[GneissWare]

Pierre,
Manganese can be removed with HCl. Waller's will not have any effect.

Many Aluminum cleaners contain a few percent of HF which will clean microcrystaline quartz off larger Quartz crystals. It may be weak enough not to remove luster. The problem is that HF is not safe at really any concentration, particularly if you don't follow all precautions.

[Pierre Joubert]

[Pierre Joubert]

Hi GneissWare, I took a low quality quartz specimen with Psilomelane and left it in pool acid (HC) for about a week. I found no notable corrosion. See photo.

[Pierre Joubert]

Since I started this thread, I have experimented a lot and, thanks to our good friend Ronnie McKenzie, discovered a very valuable acid called Aluminium Bright Cleaner. He used it to clean the monster quartz (with ajoite specimen) that was displayed at Tuscon. I hope to hear from the manufacturers soon what the composition of the acid is.
I find that this acid works very well on quartz specimens from KwaNdbele, Vredendal Lime Quarry, specimens from a certain gorge near Worcester (Western cape) and also quartz specimens from the Northern Cape.
Oxalic acid works very well for specimens from our direct area (Ceres, Western Cape).
Pool (HC) acid works well for Erongo and Brandberg quartz crystals (Oxalic acid also works very well with BB quartz specimens).
When other minerals like calcite is present (unless you want to remove that to), these acids must NOT be used.
I discovered that in different areas, the 'glue' that binds the clay is made up of different minerals and only experimenting can tell you what works for what.
My years of frustration has finally come to an end and I have a very high success rate in cleaning my quartz specimens, as I now know what cleans what.

[GneissWare]

Many aluminum cleaners contain HF or ammonium bifluoride (which is a buffered form of HF). So, check the SDS and be careful.

Psilomolene, by the way is a bit harder to remove. More sooty Mn oxides will come off with HCl.

[Pierre Joubert]

[GneissWare]

HF (hydrofluoric acid) is orders of magnitude more dangerous than HCl (hydrochoric acid, muriatic acid).