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More about beta Quartz
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Carles Curto




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PostPosted: Sep 04, 2008 06:49    Post subject: Re: More about beta Quartz  

The absence (or almost) of prism faces is not definitive to define Quartz-beta. Neat dipyramidal quartzes are common, for example, in Keuper (Triassic) layers, where, even considering possible genetic relations with the intrussion of ofites, to explain high temperature conditions would be complicate and very doubtful.
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Tracy




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PostPosted: Sep 04, 2008 08:32    Post subject: Re: More about beta Quartz  

I have a quartz-hematite combo from Guangdong which is described on the label as "alpha quartz after beta quartz." This is not scientifically correct, nor does it go so far as to refer to the quartz as a paramorph (as in the webpage we have seen), and I am interpreting it in a descriptive sense only - that is to say, "here is alpha quartz that has a form similar to beta quartz even though it is alpha." Clearly, though, this type of labeling is dangerous and misleading for the uninformed quartz collector who might not benefit from following this thread (I confess that the label to which I refer sounded much more "exotic" until this topic was posted)...
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nitana2000




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PostPosted: Sep 05, 2008 00:31    Post subject: Re: More about beta Quartz  

Hello to all, I have news for Mr. Kloprogge:

"Hi Juan,

Thanks for your email. Unfortunately this is a mistake on my website that I haven't been able to correct due to long-term illness., it is correct in the text section but not on the photos page. They are actually alpha-quartz pseudomorph after beta-quartz. When alpha-quartz is heated above 573 degrees C it changes to its polymorph beta, when cooled below 573 degrees it changes back to alpha-quartz again. Therefore it is impossible to find beta-quartz, but only alpha-quartz pseudomorphs after beta-quartz.

I hope this answers your question

Cheers
Theo."

Thank you very much Mr. Kloprogge for your answer. I wish you the best and a fast recovery of your illness.
I translate your email to the forum.

Thank you again. Thank you very much. Best regards. Juan Laureano.
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John S. White
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PostPosted: Sep 05, 2008 05:28    Post subject: Re: More about beta Quartz  

Technically the structural adjustments brought about by temperature changes are called paramorphs, not pseudomorphs. One can possess quartz crystals that are morphologically beta quartz, but they are structurally low or alpha quartz, and these have to have come from an environment that experienced extremely high temperatures, generally acid volcanic conditions.

Pseudomorphism implies the replacement, partially or totally, of the original crystal with something else. In the case of goethite after pyrite, the sulfur in pyrite has been replaced by hydrogen and oxygen.

And, as Carles pointed out, the absence of prism faces does not make a crystal a beta quartz crystal. Many low quartz crystals occur without prism faces, those from Cumbria, England, and Dalnegorsk, Russia, being good examples.

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John S. White
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PostPosted: Sep 22, 2008 06:57    Post subject: Re: More about beta Quartz  

As long as we are looking into the subject of beta quartz, I would like to share something with visitors to this site, something I was reminded of by my good friend Saul Krotki. Somehow he remembered an article that appeared in Mineralogical Record back in 1977, in volume 8, pp. 313-326, an article about some minerals from Laacher See, Germany, which are volcanic in origin.

All along in this thread we have been referring to "typical" beta quartzes as consisting of two pyramids attached base to base, formng a hexagonal dipyramid. Cumberland habit quartzes (alpha or low quartz) mimic this habit but are not identical to it because they consist of two rhombohedrons, positive and negative, which share a common central axis. Simple dipyramids, however, are not always the habit displayed by beta quartzes, as is well illustrated by the two drawings from p. 316 of the article, reproduced here. Wouldn't you love to have one of the "tailed" high quartz crystals as seen in Fig. 10?

Bellerberg, by the way, is one of the many quarries in the Laacher See area.



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John S. White
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PostPosted: Jan 05, 2009 09:21    Post subject: Re: More about beta Quartz  

This is a classic Cumberland habit quartz, which mimics the shape of beta quartz crystals, but it is indeed alpha or low temperature quartz. A close inspection will reveal that alternate pyramid faces are not the same size and this is also true of the corresponding narrow prism faces, characteristics that definitely deny this being a beta quartz crystal.


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Aymeric




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PostPosted: Feb 20, 2009 05:07    Post subject: Re: More about beta Quartz  

My, I thought I had a nice Czech Béta Quartz specimen until I read this thread.

Was I wrong ?



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Amethystine Quartz & Limonite - Studenec, Czech Republic
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John S. White
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PostPosted: Feb 20, 2009 06:13    Post subject: Re: More about beta Quartz  

Sorry to say it appears that you are wrong. What you appear to have is a very nice Cumberland habit quartz from the Czech Republic.

Welcome to the Forum, we are very pleased to have you join us.

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Pete Richards
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PostPosted: Feb 20, 2009 10:12    Post subject: Re: More about beta Quartz  

Quartz very similar to the Cumberland specimen posted by John White is also found, again on hematite, at Chub Lake, New York. Similar crystals, without the hematite, are found in ironstone concretions in the Huron River valley in northern Ohio. In both cases these are alpha quartz.

Actually, even beta quartz is not beta quartz. Beta quartz only exists at high temperatures (above about 570°C). Below that temperature, the structure shifts slightly to that of alpha quartz, so crystals that started out as beta quartz become complex intergrowths of alpha quartz domains that are twinned relative to each other according to the Dauphiné twin law. The transformation is a very easy one, since it does not require breaking any chemical bonds, and thus it takes place quickly and reliably once the appropriate temperature is reached.

The believable "beta" quartz examples I have seen are frosted on the crystal faces and translucent. Apparently beta quartz most commonly grows as crystals within a lava - phenocrysts - although it sometimes grows in cavities in rhyolites as well.

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Aymeric




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PostPosted: Feb 21, 2009 06:14    Post subject: Re: More about beta Quartz  

No need to be sorry John, I might be wrong, but at least I've learned something ! now I know what a Cumberland habit is, thank you !
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marco campos-venuti




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PostPosted: Mar 08, 2016 06:48    Post subject: Re: More about beta Quartz  

Hi all, nice theme!
This is a specimen of the "Porfido granodioritico" from Elba Island, Italy. It is a magmatic body of granodiorite characterized by big phenocrystals of orthoclase (not in this sample) and phenocrystals of quartz, associated to the main body of the Monte Capanne pluton, famous for its pegmatites with elbaites.
In the specimens the quartz crystals are partially freed from its magmatic matrix due to wind erosion.
If I understand well, this can be a beta quartz (alpha pseudo after beta). The symmetry is strictly hexagonal, but the prism is present.



Imagen1.jpg
 Mineral: Alpha Quartz pseudo after Beta Quartz in granodiorite matrix
 Locality:
Capo di Fonza, Elba Island, Livorno Province, Tuscany, Italy
 Dimensions: specimen 14 cm, crystals about 1 cm
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John S. White
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PostPosted: Mar 08, 2016 07:14    Post subject: Re: More about beta Quartz  

Beta quartz crystals can exhibit prisms, no problem. Your crystals do appear to be pseudomorphs after beta quartz.
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Pete Modreski
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PostPosted: Mar 08, 2016 12:34    Post subject: Re: More about beta Quartz  

Thank you for showing us this particularly good specimen, Marco. It's very unusual to see the beta quartz* crystals well exposed on the matrix this way!

*and we all will understand, of course, that if I write "beta quartz" for brevity, I really mean "alpha quartz paramorphs after beta quartz".
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