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Malcolm Southwood
Joined: 04 Feb 2011
Posts: 15
Location: Melbourne



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Posted: Mar 23, 2013 21:27 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Ahh Pete,
A senior moment - chalcotrichite indeed!
I'm very interested in this theme of elongated crystals, and would like to explore it a little further. I, too, have examples of these among my Weardale fluorites, and the sometimes-cited explanation of "asymmetry in the growth environment" makes intuitive sense, but doesn't in any way explain the phenomenon.
Geometrically, cubes can tesselate perfectly, to form a "bar" of any size or shape with three axes of symmetry still at 90 degrees to one another. Should we perhaps think of these elongated fluorite crystals as a "stack" of cubes?
Also, Kantor (in the reference I cited in my earlier posting) talks about what he calls the "corner octahedron" model for development of skeletal crystals in the isometric system. I won't begin to attempt an explanation of that here, but it seemed to me not a million miles away from the idea of "stacked cubes", but with the stacking very much ordered by the symmetry requirements of the mineral concerned.
Thanks for your thoughts
mal
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Gail

Joined: 21 Feb 2008
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Location: Texas, Lone Star State.



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Posted: Mar 23, 2013 23:43 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Blackdene mine.
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_________________ Minerals you say? Why yes, I'll take a dozen or so... |
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Ru Smith
Joined: 13 Oct 2012
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Posted: Mar 23, 2013 23:46 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Nice.
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Jordi Fabre
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Posted: Mar 24, 2013 06:37 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Already corrected your "senior moment" Mal ;-) Now is:
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ian jones

Joined: 29 Jul 2009
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Location: london



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Posted: Mar 24, 2013 06:50 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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A very quick picture of another elongated Blackdene fluorite with quartz on the LH side. Never common although for some reason, Blackdene seemed to produce them.
Now off to the airport to get away from the cold here in the UK for a few days.
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Fluorite Blackdene Mine, Weardale, Co Durham, UK height 9cm |
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Ru Smith
Joined: 13 Oct 2012
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Posted: Mar 24, 2013 11:54 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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So that's intriguing. What favoured this growth habit at Blackdene and Boltsburn and not at the other mines in the district (bar rare exceptions)? Enjoy the sun!
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Ru Smith
Joined: 13 Oct 2012
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Posted: Mar 24, 2013 12:15 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Pete Richards wrote: | Our messages may have crossed... but those oscillations are typical, and I presume they represent small changes in the relative growth rates of fluorite and pyrite. |
Yes, we posted simultaneously. The shared "microstratigraphy" of the pyrite columns confirms your balanced growth interpretation. I had never seen this before and yesterday was the first time I looked so closely at that particular crystal. Are there any "brackets" on possible growth rates available from lab work (or any other source)?
I thought to take a look at growth zoning patterns in the elongate crystals to look for further clues on growth patterns. I can see nothing in the Boltsburn crystal, but the Blackdene one is interesting. Two of the long faces grew much faster (one faster than the other) than the other two, such that the early core of the crystal is "left behind" against one long edge. Perhaps this is the explanation for Jesse's yellow corner zone in his Rogerley crystal over on the Fluorite growth zoning thread.
Dissection of such a zoned elongate crystal would be revealing.
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Fluorite Blackdene Mine, Ireshopeburn, Weardale, Co Durham, UK. 95 mm specimen with 45 mm elongate fluorite (L/W = 5). |
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Steve Maslansky
Joined: 01 Mar 2013
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Location: Prescott, Arizona



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Posted: Mar 24, 2013 12:25 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Here is a example from the Denton Mine of Illinois
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Fluorite on sphalerite Denton Mine, Hardin County, Illinois, USA 4 x 4 inches |
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Jordi Fabre
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Posted: Mar 24, 2013 12:54 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Double-dealing: elongated and etched! ;-)
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Fluorite with Calcite Annabel Lee Mine, Hardin County, Illinois, USA Specimen size: 7.8 × 6.2 × 3.1 cm Mined on 05/17/1985 Former collection of James Catmur Fluorescent long & short UV
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Jesse Fisher

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Posted: Mar 24, 2013 13:56 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Ru - the Rogerley "yellow corners" are always on an outside corner of the crystal, never at the base or core. Also, they often occur on crystals that are otherwise fairly equant in shape, and show no suggestion of preferential growth in a particular direction.
It occurred to me that, while twinning is common in North Pennines fluorite, the examples of highly elongate crystals I've seen are usually untwinned. Looking through the collection, I found a few examples of twinned crystals that show a tabular habit, but nothing as extreme as the Boltsburn and Blackdene crystals previously posted. Below is one from the Boltsburn Mine. I also have a few, though much smaller examples from the Rogerley.
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Fluorite Boltsburn Mine, Rookhope, Weardale, England 11x8x8 cm overall size penetration-twinned crystal showing elongate habit |
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Mark Ost

Joined: 18 Mar 2013
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Posted: Mar 24, 2013 14:32 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Spectacular. My Goodness.
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Malcolm Southwood
Joined: 04 Feb 2011
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Posted: Mar 24, 2013 15:29 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Jordi, thanks for the correction, (thereby sparing future blushes!)
Pete,
I'd like to revisit, for a moment, the screw dislocation idea for these elongated crystals. Radovan (2004, Rocks and Minerals 79 (6) pp 415-417) attributes the development of vicinal faces and growth hillocks in fluorite to spiral growth as a result of such dislocations. Surely this would suggest that the mechanism might not be limited to whisker crystals?
Cheers
mal
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Jordi Fabre
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Pete Richards
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Posted: Mar 24, 2013 18:50 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Malcolm Southwood wrote: |
I'd like to revisit, for a moment, the screw dislocation idea for these elongated crystals. Radovan (2004, Rocks and Minerals 79 (6) pp 415-417) attributes the development of vicinal faces and growth hillocks in fluorite to spiral growth as a result of such dislocations. Surely this would suggest that the mechanism might not be limited to whisker crystals?
Cheers
mal |
You are right that screw dislocations lead to spiral growth on macroscopic crystals, and in fact they are probably the main promoter of growth in many environments where the level of supersaturation is low, because spiral growth eliminates the need to nucleate new layers of atoms, which is the growth rate limiting step in classical layered growth mechanism (in the absence of screw defects and their resulting "spiral staircase" of a single atomic layer).
The problem is that screw defects are abundant - a few to millions per square centimeter. And they should be expected to occur in roughly the same density intersecting all faces of the same form (e.g. a cube). They may promote growth overall, but unless they are selectively concentrated perpendicular to one cube face, they will not promote differential growth. I'm not aware of anyone suggesting a mechanism by which they are selectively present in one direction in macroscopic crystals.
In whisker crystals, it does seem to be the case that whiskers are promoted by a single screw defect.
_________________ Collecting and studying crystals with interesting habits, twinning, and epitaxy |
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Malcolm Southwood
Joined: 04 Feb 2011
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Location: Melbourne



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Posted: Mar 24, 2013 20:04 Post subject: Re: Elongate and tabular fluorite crystals - (7) |
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Thanks Pete,
That's helpful.
mal
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