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Elongate and tabular fluorite crystals - (7)
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Malcolm Southwood




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PostPosted: Mar 23, 2013 21:27    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Ahh Pete,
A senior moment - chalcotrichite indeed!

I'm very interested in this theme of elongated crystals, and would like to explore it a little further. I, too, have examples of these among my Weardale fluorites, and the sometimes-cited explanation of "asymmetry in the growth environment" makes intuitive sense, but doesn't in any way explain the phenomenon.

Geometrically, cubes can tesselate perfectly, to form a "bar" of any size or shape with three axes of symmetry still at 90 degrees to one another. Should we perhaps think of these elongated fluorite crystals as a "stack" of cubes?

Also, Kantor (in the reference I cited in my earlier posting) talks about what he calls the "corner octahedron" model for development of skeletal crystals in the isometric system. I won't begin to attempt an explanation of that here, but it seemed to me not a million miles away from the idea of "stacked cubes", but with the stacking very much ordered by the symmetry requirements of the mineral concerned.

Thanks for your thoughts
mal
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Gail




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PostPosted: Mar 23, 2013 23:43    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Blackdene mine.


IMG_5745.jpg
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IMG_5745.jpg



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Ru Smith




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PostPosted: Mar 23, 2013 23:46    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Nice.
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Jordi Fabre
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PostPosted: Mar 24, 2013 06:37    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

In https://www.mineral-forum.com/message-board/viewtopic.php?p=29890#29890 Malcolm Southwood wrote:
...A senior moment - chalcotrichite indeed!...

Already corrected your "senior moment" Mal ;-) Now is:
In https://www.mineral-forum.com/message-board/viewtopic.php?p=29871#29871 Malcolm Southwood wrote:
...By coincidence I've just been doing some reading on the development of skeletal cuprite crystals and, ultimately, acicular ones (chalcotrichite)...
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ian jones




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PostPosted: Mar 24, 2013 06:50    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

A very quick picture of another elongated Blackdene fluorite with quartz on the LH side. Never common although for some reason, Blackdene seemed to produce them.

Now off to the airport to get away from the cold here in the UK for a few days.



Elongated Blackdene 800p.jpg
 Description:
Fluorite
Blackdene Mine, Weardale, Co Durham, UK
height 9cm
 Viewed:  44015 Time(s)

Elongated Blackdene 800p.jpg


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Ru Smith




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PostPosted: Mar 24, 2013 11:54    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

So that's intriguing. What favoured this growth habit at Blackdene and Boltsburn and not at the other mines in the district (bar rare exceptions)? Enjoy the sun!
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Ru Smith




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PostPosted: Mar 24, 2013 12:15    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Pete Richards wrote:
Our messages may have crossed... but those oscillations are typical, and I presume they represent small changes in the relative growth rates of fluorite and pyrite.


Yes, we posted simultaneously. The shared "microstratigraphy" of the pyrite columns confirms your balanced growth interpretation. I had never seen this before and yesterday was the first time I looked so closely at that particular crystal. Are there any "brackets" on possible growth rates available from lab work (or any other source)?

I thought to take a look at growth zoning patterns in the elongate crystals to look for further clues on growth patterns. I can see nothing in the Boltsburn crystal, but the Blackdene one is interesting. Two of the long faces grew much faster (one faster than the other) than the other two, such that the early core of the crystal is "left behind" against one long edge. Perhaps this is the explanation for Jesse's yellow corner zone in his Rogerley crystal over on the Fluorite growth zoning thread.

Dissection of such a zoned elongate crystal would be revealing.



Elongate fluorite end view.jpg
 Description:
Fluorite
Blackdene Mine, Ireshopeburn, Weardale, Co Durham, UK.
95 mm specimen with 45 mm elongate fluorite (L/W = 5).
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Elongate fluorite end view.jpg


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Steve Maslansky




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PostPosted: Mar 24, 2013 12:25    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Here is a example from the Denton Mine of Illinois


M711.jpg
 Description:
Fluorite on sphalerite
Denton Mine, Hardin County, Illinois, USA
4 x 4 inches
 Viewed:  33801 Time(s)

M711.jpg


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Jordi Fabre
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PostPosted: Mar 24, 2013 12:54    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Double-dealing: elongated and etched! ;-)


Florite with Calcite - Annabel Lee Mine_Hardin County_Illinois_USA.jpg
 Description:
Fluorite with Calcite
Annabel Lee Mine, Hardin County, Illinois, USA
Specimen size: 7.8 × 6.2 × 3.1 cm
Mined on 05/17/1985
Former collection of James Catmur
Fluorescent long & short UV

Photo: Reference Specimens
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Florite with Calcite - Annabel Lee Mine_Hardin County_Illinois_USA.jpg


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Jesse Fisher




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PostPosted: Mar 24, 2013 13:56    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Ru - the Rogerley "yellow corners" are always on an outside corner of the crystal, never at the base or core. Also, they often occur on crystals that are otherwise fairly equant in shape, and show no suggestion of preferential growth in a particular direction.

It occurred to me that, while twinning is common in North Pennines fluorite, the examples of highly elongate crystals I've seen are usually untwinned. Looking through the collection, I found a few examples of twinned crystals that show a tabular habit, but nothing as extreme as the Boltsburn and Blackdene crystals previously posted. Below is one from the Boltsburn Mine. I also have a few, though much smaller examples from the Rogerley.



F326-6488r.jpg
 Description:
Fluorite
Boltsburn Mine, Rookhope, Weardale, England
11x8x8 cm overall size
penetration-twinned crystal showing elongate habit
 Viewed:  33694 Time(s)

F326-6488r.jpg


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Mark Ost




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PostPosted: Mar 24, 2013 14:32    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Spectacular. My Goodness.
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Malcolm Southwood




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PostPosted: Mar 24, 2013 15:29    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Jordi, thanks for the correction, (thereby sparing future blushes!)

Pete,
I'd like to revisit, for a moment, the screw dislocation idea for these elongated crystals. Radovan (2004, Rocks and Minerals 79 (6) pp 415-417) attributes the development of vicinal faces and growth hillocks in fluorite to spiral growth as a result of such dislocations. Surely this would suggest that the mechanism might not be limited to whisker crystals?

Cheers
mal
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Jordi Fabre
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PostPosted: Mar 24, 2013 15:41    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Malcolm Southwood wrote:
...I'd like to revisit, for a moment, the screw dislocation idea for these elongated crystals...

Recommended reading: Inclusions of spiral or helical growth and screw dislocations
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Pete Richards
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PostPosted: Mar 24, 2013 18:50    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Malcolm Southwood wrote:

I'd like to revisit, for a moment, the screw dislocation idea for these elongated crystals. Radovan (2004, Rocks and Minerals 79 (6) pp 415-417) attributes the development of vicinal faces and growth hillocks in fluorite to spiral growth as a result of such dislocations. Surely this would suggest that the mechanism might not be limited to whisker crystals?

Cheers
mal


You are right that screw dislocations lead to spiral growth on macroscopic crystals, and in fact they are probably the main promoter of growth in many environments where the level of supersaturation is low, because spiral growth eliminates the need to nucleate new layers of atoms, which is the growth rate limiting step in classical layered growth mechanism (in the absence of screw defects and their resulting "spiral staircase" of a single atomic layer).

The problem is that screw defects are abundant - a few to millions per square centimeter. And they should be expected to occur in roughly the same density intersecting all faces of the same form (e.g. a cube). They may promote growth overall, but unless they are selectively concentrated perpendicular to one cube face, they will not promote differential growth. I'm not aware of anyone suggesting a mechanism by which they are selectively present in one direction in macroscopic crystals.

In whisker crystals, it does seem to be the case that whiskers are promoted by a single screw defect.

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Malcolm Southwood




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PostPosted: Mar 24, 2013 20:04    Post subject: Re: Elongate and tabular fluorite crystals - (7)  

Thanks Pete,
That's helpful.
mal
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